N,N-Dimethyl-4-[(E)-phenyliminomethyl]aniline

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N,N-Dimethyl-4-[(E)-phenyl­imino­meth­yl]aniline

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2,3-Dimethyl-N-[(E)-4-nitro­benzyl­idene]aniline

In the title compound, C(15)H(14)N(2)O(2), the aromatic rings are oriented at a dihedral angle of 24.52 (5)°. The dihedral angle between the nitro group and its parent benzene ring is 9.22 (16)°. In the crystal, mol-ecules inter-act through aromatic π-π stacking inter-actions [centroid-centroid separations = 3.8158 (14) and 3.9139 (14) Å].

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In the title mol-ecule, C(25)H(26)N(4)O, the piperidine ring adopts a chair conformation, with the plane through the four coplanar atoms making dihedral angles of 84.76 (6), 82.28 (5) and 81.91 (6)° with the pyridine-ring and the phenyl rings at the 2 and 6 positions, respectively. The pyridine ring makes dihedral angles of 64.13 (8) and 10.75 (8)° with the phenyl rings at the 2 and 6 positions...

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(E)-1,3-Dimethyl-2,6-di­phenyl­piperidin-4-one O-(phen­oxy­carbon­yl)oxime

The title piperidine derivative, C26H26N2O3, has an E conformation about the N=C bond. The piperidine ring has a chair conformation and its mean plane is almost perpendicular to the attached phenyl rings, making dihedral angles of 87.47 (9) and 87.34 (8)°. The planes of these two phenyl rings are inclined to one another by 60.38 (9)°. The plane of the terminal phenyl ring is tilted at an angle ...

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In the title compound, C(7)H(12)N(2)O(2)S(2), the conformation of the dithia-cyclo-pentane ring is a half-chair, with a total puckering amplitude Q(T) = 0.473 (5) Å. Inter-molecular C-H⋯N and C-H⋯O inter-actions help to establish the packing.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809003791